Scientific Publications

19.
 

Mews, N. M.; Hörner, G.; Schubert, H.; Berkefeld, A., Tuning of Thiyl/Thiolate Complex Near-Infrared Chromophores of Platinum through Geometric Constraints. Inorg. Chem. (Forum Article), 2018, DOI: 10.1021/acs.inorgchem.8b00122. Access Paper

18.
 

Koch, F.; Berkefeld, A., Reactant or Reagent? Oxidation of H2 at Electronically Distinct Nickel-Thiolate Sites
[Ni2(mu-SR)2]+ and [Ni-SR]+. Dalton Trans. 2018, DOI: 10.1039/C8DT00275D. Access Paper

17.
 

Koch, F.; Berkefeld, A.; Speiser, B., Schubert, H., Mechanistic Aspects of Redox-Induced Assembly and Disassembly of S-Bridged [2M-2S] Structures. Chem. Eur. J. 2017, 23, 16681-16690. Access Paper

16.
 

Mews, N. M.; Berkefeld, A.; Hörner, G.; Schubert, H., Controlling Near-Infrared Chromophore Electronic Properties through Metal-Ligand Orbital Alignment. J. Am. Chem. Soc. 2017139, 2808-2815. Access Paper

15.
 

Koch, F.; Berkefeld, A.; Schubert, H.; Grauer, C., Redox and Acid-Base Properties of Binuclear 4-Terphenyldithiophenolate Complexes of Nickel. Chem. Eur. J. 2016, 14640-14647. Access Paper

14.

 

Koch, F.; Schubert, H.; Sirsch, P.; Berkefeld, A., Binuclear Complexes of Ni(I) from 4-Terphenyldithiophenol.

Dalton Trans. 2015, 44, 13315-13324. Open Access


13.

 

Berkefeld, A.; Piers, W. E.; Parvez, M.; Castro, L.; Maron, L.; Eisenstein, O., Decamethylscandocinium-hydrido-(perfluorophenyl)borate: Fixation and Tandem Tris(perfluorophenyl)borane

Catalyzed Deoxygenative Hydrosilation of Carbon Dioxide. Chem. Sci. 2013, 4, 2152.

12.

Frank, A.; Berkefeld, A.; Drexler, M.; Möller, H. M.; Exner, T. E., Small Changes-Huges Influences: NMR Chemical Shifts of Ni(II) Complexes with Polar Substrates. Int. J. Quantum Chem. 2013, 113, 1787-1793.

11.
 

Berkefeld, A.; Piers, W. E.; Parvez, M.; Castro, L.; Maron, L.; Eisenstein, O., Carbon Monoxide Activation via O-bound CO Using Decamethylscandocinium Hydridoborate Ion Pairs. J. Am. Chem. Soc. 2012, 134, 10843-10851.

10.
 

LeBlanc, F. A.; Berkefeld, A.; Piers, W. E.; Parvez, M., Reactivity of Scandium β-Diketiminate Alkyl Complexes with Carbon Dioxide. Organometallics 2012, 31, 810.

9.

 

Xiong, Y.; Yao, S.; Inoue, S.; Berkefeld, A.; Driess, M., Taming the Germyliumylidene [CIGe:]+ and Germathionium [CIGe=S]+ Ions by Donor-Acceptor Stabilization Using 1,8-Bis(tributylphosphazenyl)naphthalene.
Chem. Commun. 2012, 48, 12198.

8.
 

Berkefeld, A.; Piers, W. E.; Parvez, M., Tandem Frustrated Lewis Pair/ Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide. J. Am. Chem. Soc. 2010, 132, 10660.

7.
 

Berkefeld, A.; Drexler, M.; Möller, H. M.; Mecking, S., Mechanistic Insights on the Copolymerization of Polar Vinyl Monomers with Neutral Ni(II) Catalysts. J. Am. Chem. Soc. 2009, 131, 12613.

6.
 

Berkefeld, A.; Mecking, S., Deactivation Pathways of Neutral Ni(II) Polymerization Catalysts.
J. Am. Chem. Soc. 2009, 131, 1565.

5.
 

Berkefeld, A.; Möller, H. M.; Mecking, S., Unusual Reactivity of N,N,N’,N’-Tetramethylethylenediamine Coordinated Neutral Ni(II) Polymerization Catalysts. Organometallics 2009, 28, 4048.

4.
 

Berkefeld, A.; Mecking, S., Coordination Copolymerization of Polar Vinyl Monomers H2C=CHX.
Angew. Chem., Int. Ed. 2008, 47, 2538.

3.
 

Korthals, B.; Berkefeld, A.; Ahlmann, M.; Mecking, S., Catalytic Polymerization of Butadiene in Aqueous Systems with Cationic Nickel(II) Complexes. Macromolecules 2008, 41, 8332.

2.

 

Yu, S.-M.; Berkefeld, A.; Göttker-Schnetmann, I.; Müller, G.; Mecking, S., Synthesis of Aqueous Polyethylene Dispersions with Electron-Deficient Neutral Nickel(II) Catalysts with Enolatoimine Ligands.
Macromolecules 2007, 40, 421.

1.
 

Berkefeld, A.; Mecking, S., Mechanistic Studies of Catalytic Polyethylene Chain Growth in the Presence of Water. Angew. Chem., Int. Ed. 2006, 45, 6044.